Tibiao was part of Nalupa from 1596 to 1840. Nalupa, with its central government in present-day Jinalinan controlled the area of what is now Tibiao, Barbaza, and Laua-an. In early 1730, Nalupa gradually depopulated due to the Moro pirate attacks. By 1733, Culasi had direct control of Nalupa and Pandan. In 1796, Nalupa ceded from Culasi. As an arrabal, notable village chieftains were Paris, Oguid Pagsuguiron, and Nicolas Amar (1818).

In 1997, the First Philippine International Whitewater Kayaking Cup (Participated by 11 countries ) held in Tibiao River.

Located in the town of Tibiao Antique, Tibiao River is an eco-adventure tourist spot perfect for friends and family having a vacation. It's just a few hours away from Boracay, Iloilo, Kalibo and Caticlan. Its pristine, cool waters are unique on its own; making it the perfect kayaking river for beginners and advanced white water rafters.

One of the most exciting things to do in Tibiao River is to try kayaking. Perfect for thrill-seekers, courses areavailable for one's learning and enjoyment. Kayaking can be done alone or in tandem, and it totally depends on your preference.